Golounin Alexander Vasilevich

Date of birth: August 2, 1940. Russian page OBJECTIVE M I work in organic chemistry 35 years. More then 20 new (unknown to all) compounds, many molecular complexes and aromatic ions were synthesized by me during this time. I was the first who showed the possibility of the aryl alkylation of aromatic compounds (benzol) by means of phenols and their derivations. A method of the full bromation of aromatic compounds was developed: benzol, toluene, xylenes, chlorbenzenes, diphenyl ether and many other. The fire retardant – pentabromephenoxyethanol was synthesized at the first time at the world. The methods of the alkylation and the acylation of pentabromephenol were developed. The technology of the manufacturing of the simm-tetramethylphenol was developed also. The new simple method of the alkylation of long-chain amines was patented. The new alkylated a-thiopicolineanilides were synthesized. The new systems for the extraction of Ga and Al from the water alkaline solutions were proposed. Several unknown pyrocatechols were synthesized. The influence of the nitrogen bases on the extraction of ions Me(2+) by means of carboxylic acids were studied. It was shown , At the first time (in organic chemistry) was shown, that alkylated phenols undergo phenol-diene regrouping when AlHal are present in the system. The cyclohexadienone complexes formed during such reactions. The thermodynamic parameters of the complexation of methylated phenols with AlBr3 were calculated. The method of the estimation of the thermodynamic parameters of the phenol- cyclohexadienone tautomerism was proposed for the first time. It is found the formation of chelates during the interaction of ortho- nitrophenols with AlBr3. it is found the functional dependence of the extraction of essential oils and bioactive substances on the dispersibility of the plant materials. The method of the manufacturing of clear tannins from the cedar nutshell was proposed. The method of the manufacturing of the top-quality melanin from the natural raw materials was developed. The method of the selective di- alkylation of the guanidine was developed, also. A new system (containing guanidine derivations), allowing completely to extract Au from water alkaline solutions were found. 2 monographs were published. SUMMARY of EMPLOYMENT Assistant, research engineer, senior staff scientist, senior lecturer, head research officer, professor, chief of a chair. EDUCATION 1963-1968 Altaian Politecnic Institute, Chemical-Technology Faculty, Speciality: manufacturing engineer 1969-1972 Novosibirsk Institute of Organic Chemistry, Russian Academy of Science, Postgraduate course, PhD RESEARCH INTERESTS Physical-organic Chemistry WORK HISTORY 1972-1974 Novosibirsk Institute of Organic Chemistry, Russian Academy of Science, research engineer. The Synthesis of oil depressants. 1974-1976 The Institute of Chloric Industry in Bashkiria Republic. The synthesis of fire retardants on the basis of perbromaromatic compounds. 1976-1978 The Institute of Textile Industry.in Barnaul city. The faculty member 1978-1985 The Krasnoyarsk State University, Chemical Faculty, the Department of Organic Chemistry. 1985-for now the Laboratory of Hydrometallurgy processes, Institute Chemistry and Chemical Technology, Siberian Department of Russian Academy Science, Krasnoyarsk. LANGUAGE SKILLS Mother language: Russian Foreign Language: English (I can to read English texts by means of dictionary) SELF INTRODUCTION LETTER I was born at 2 August 1940 at the village Ivanovskaya (Samgensky region at the Vologodskaya province) at the teacher family. I graduated a secondary school at 1958. From 1958 to October 1960 I worked. From October 1960 to September 1963 military service. From 09.1963 to 06.1968 I studied at the Altaysky Polytechnic Institute. I graduated the institute and got the industrial engineer diploma on the specialty artificial fibres. From 07.1968 to 09.1969 I worked as assistant on the organic chemistry chair in the institute. From 09.1969 to 10.1972 I study in the postgraduate courses at the Novosibirsk Institute of Organic Chemistry, Russian Academy of Science. From 10.1972 to 07.1974 I worked as the research engineer at the institute. At 05.1974 I defended the dissertation on the degree of candidate of chemical science. From 07.1974 to 07.1976 I worked as senior staff scientist at the institute of chlorine industry in Bashkiria. From 1976 to 1978 I worked as senior teacher at the textile industry institute in Barnaul city. From 06.1978 to 03.1985 I worked as senior lecturer at the Krasnoyarsk State University. From 03.1984 to present time I work at the Institute of Chemistry and Chemical Technology, Siberian Department of Russian Academy of Science. At 1998 I defended the dissertation on the degree of doctor of chemical science. From 2000 to present time I am professor. I lecture the course of organic chemistry in Krasnoyarsk State Agrarian University. I am a head of the organic chemistry chair at the University, also. I am married. I have 2 Childs. My son is 29 year old, my daughter is 20 year old. The list of most important publications Golounin A.V , Shchedrin YS, Fedorov VA Complexes of cyclogexadieno-new with aluminum bromide / / Russian Journal of Organic Chemistry 2002. Vol.72. Iss.6. P.975-977. Golounin A.V, Tovbis MS, Zakharova OV, Ivanova EA Thermodynamics of nitrozofenol tautomerism. / / Proceedings of the universities Ser. Chemistry .2002, Vol.45. Iss.6. P. 46-49 Golounin A.V, Sokolenko VA, Zakharova O., Shor, EA, MS Tovbis Complexes of ortho-nitrophenols with aluminum bromide in nonaqueous solutions. // Russian Journal of Applied Chemistry 2007. Vol.80. Iss.6. P.1040-1042. Golounin AV, Sokolenko VA, Tovbis MS, Zakharova OV Nitronaftol complexes with aluminum bromide. / / Russian Journal of Applied Chemistry 2007. Vol.80. Iss.6. P.1040-1042 Kononov YS, Golounin A.V, Pashkov GL, Kuklina U.F., Mikhailenko, MA, Tsupinin DV Application of resin with guanidine functional groups in the hydrometallurgy of gold. / / Russian Journal of Applied Chemistry 2005. Vol.78. Iss.10. P. 1739-1741. Golounin A.V, Larionova I Extraction of gold from alkaline solutions by amines and guanidines.. / / Proceedings of the universities Ser. Chemistry and Chem. Tech. 2006 Vol.49, Iss. 7. P. 93-95. Golounin A. V, Kononov YS, Larionova IA Application of nitrogenous bases to extraction of the gold cyanide complexes / / Chemical Technology. 2007.Vol.8. Number 6. P.241-244. Golounin A.V. Extraction (sorption) of gold with amines, quaternary ammonium salts and other nitrogenous bases // Proceedings of the First International Congress «Non-Ferrous metals of Siberia-2009». Edited by Gennady L. Pashkov Peter V. Polyakov – Krasnoyarsk: Verso, 2009. – P. 524-527. Golounin A.V., Sokolenko V.A., at, al. Catalytic Transformtion of the Alkylation Products of Naphtalene. // Coke and Chemystri 2009.vol.52.№ 3. P. 121-123. Golounin A.V.,Marakushina E.N., Khramenko S.A. Emission of Carcinigenic PAH during of coal tar pitch.// Coke and Chemystri 2010.vol.53.№ 3. P. 32-36.